1 00:00:04,340 --> 00:00:13,760 So yesterday we had an awkwardness about this formula here because what overage arrived disagreed in the ordering here from what's in the book. 2 00:00:13,940 --> 00:00:20,030 And it just should reassure you that what I derived was correct and what's in the book is correct. 3 00:00:20,480 --> 00:00:25,310 And it's quite instructive, too, because these are important formulae, so it's good to have them in your mind. 4 00:00:25,910 --> 00:00:31,969 So let's just let's just understand how it comes about. 5 00:00:31,970 --> 00:00:39,860 The both of these are right. If you if so, what's happened between these two is that these things have been swapped in their order. 6 00:00:39,860 --> 00:00:43,340 But crucially, also, these things have been swapped. 7 00:00:44,120 --> 00:00:48,590 So if I go from here, I pick up a minus sign. 8 00:00:49,160 --> 00:00:56,209 If I simply invert the two operators, j and vs is just an arbitrary vector. 9 00:00:56,210 --> 00:00:59,600 Okay. It could be x, it could be P, it could be j, it could be whatever. 10 00:00:59,630 --> 00:01:05,450 Right? So if I swap these two operators, of course I pick up a, I pick up a minus sign, 11 00:01:06,860 --> 00:01:14,630 but then I can pick up a matching minus sign on the right side by swapping these two indices of the Epsilon symbol. 12 00:01:15,710 --> 00:01:22,910 So that's minus i Sigma K, Epsilon, j i k v k. 13 00:01:24,260 --> 00:01:35,180 And now I can say to myself, well, so, so, so I now have this formula from this formula of to to derive this formula except the what here is called I, 14 00:01:35,210 --> 00:01:43,460 which is the index on J and the index on the first index on epsilon is here called Little J and what here 15 00:01:43,460 --> 00:01:51,280 is called J being the middle index on Epsilon and the index on the vector operator is here called II. 16 00:01:51,290 --> 00:01:55,249 So it's a mere relabelling of what appears at the bottom. So these two familiar both? 17 00:01:55,250 --> 00:01:59,250 Correct. Okay. 18 00:01:59,370 --> 00:02:16,890 So. We just need to pull together. 19 00:02:16,900 --> 00:02:24,670 We really have everything now. We just need to pull together the results that we have and just calmly understand the physical significance of them. 20 00:02:30,660 --> 00:02:37,050 So we've discovered that these operators, like the momentum and the angular momentum, are associated with with displacements. 21 00:02:37,710 --> 00:02:42,060 They generate they're the generators of displacements. The momentum generates. 22 00:02:42,390 --> 00:02:46,110 You have a which shoves your system. It doesn't literally shove your system. 23 00:02:46,290 --> 00:02:50,699 It makes a new system that's translated that's the same as the old one, 24 00:02:50,700 --> 00:02:57,629 except its location is being incremented by a the incremental operators make a new system which is the same as your old system, 25 00:02:57,630 --> 00:03:01,740 except they've been rotated around the origin by some angle. 26 00:03:03,080 --> 00:03:12,530 And we have already seen that when the that when the momentum operator commits with the Hamiltonian, 27 00:03:12,530 --> 00:03:19,100 when one of these observables commits with a Hamiltonian, we have a conserved quantity and we have good quantum numbers and things like that. 28 00:03:20,150 --> 00:03:30,049 So what's the connection? Okay, so if so, let's say if P commits with H, what does that mean? 29 00:03:30,050 --> 00:03:37,730 That very easily implies that U of A the translation operator is going to compute with H because this 30 00:03:37,730 --> 00:03:47,720 operator right is e to the minus i a dot p pon h bar is a function of p and therefore it commutes. 31 00:03:48,080 --> 00:03:53,600 If h commits with p commits then the function of p. So if we have sorry. 32 00:03:53,600 --> 00:03:58,380 If if this equals nought, then this equals nought. 33 00:03:58,400 --> 00:04:02,510 Now, what does that, uh. What does that tell us? 34 00:04:02,510 --> 00:04:04,309 To see what it tells. What it tells us. 35 00:04:04,310 --> 00:04:13,730 We we have to think about the unitary operator associated with H because H is an observable and it's associated with the unitary operator. 36 00:04:15,530 --> 00:04:18,589 Each of the minus i h. Upon H. 37 00:04:18,590 --> 00:04:24,740 Bar t. Which we're going to call U of T. 38 00:04:25,520 --> 00:04:28,220 What's this, operator? Well, we know. 39 00:04:28,310 --> 00:04:44,120 We already know that IXI at time t is equal to the sum and each of the minus i e and over h for t times n that way. 40 00:04:44,210 --> 00:04:51,110 This is our standard expression for solving our standard means of solving the time dependent Schrodinger equation 41 00:04:51,110 --> 00:04:56,479 is to decompose the given state into a linear superposition of energy ion states as any particular time, 42 00:04:56,480 --> 00:05:02,570 for example, at t equals zero and then evolves by multiplying each term in the series by this exponential here. 43 00:05:03,500 --> 00:05:14,750 But we can see that this could also be written as e to the minus i h t upon h bar times sum and. 44 00:05:16,080 --> 00:05:24,090 Ian Wright because when this linear operator looks at this sum here, it passes. 45 00:05:24,090 --> 00:05:30,719 It's a linear operator, so it can be distributed, pass through these ends and look at each one of these things than H looks at it. 46 00:05:30,720 --> 00:05:35,550 I can get in and it says, Aha, that's my, I can get e n it returns, 47 00:05:35,820 --> 00:05:43,950 it returns e and times the number n and then you go and there you go, you have that. 48 00:05:45,030 --> 00:05:50,430 So this operator u of T is is very is a crucial operator. 49 00:05:51,360 --> 00:05:54,990 It's the thing that evolves you forward in time any state. 50 00:05:58,220 --> 00:06:01,280 This is nothing new. This is just a repackaging of old results. 51 00:06:02,390 --> 00:06:07,490 So the unitary operator associated with the observable time moves you forward in time. 52 00:06:08,020 --> 00:06:12,500 If it carries you from today into tomorrow or whatever. 53 00:06:12,530 --> 00:06:20,210 Right. So. If so, let's just repeat this. 54 00:06:20,220 --> 00:06:31,980 If P comma h equals nought, then that implies and indeed is implied by that the unitary operates a u of a commutes with the unitary operator u of t. 55 00:06:34,300 --> 00:06:41,110 Right. This is the thing that moves you forward in time. This is the thing that makes you a new system shoved along the bench by a. 56 00:06:42,720 --> 00:06:51,930 So what does that tell you? That tells you that take take the state of your system and evolve it in time and then shove 57 00:06:51,930 --> 00:06:59,610 it along the desk and you will have exactly the same state as if you take your system. 58 00:07:02,200 --> 00:07:05,020 Shove it along the bench and then evolve it in time. 59 00:07:05,560 --> 00:07:12,130 It says that whether you let it evolve here and then move it to its point where you want to have it, 60 00:07:13,510 --> 00:07:19,720 that is this that will give you the same results as if you move it now and let it evolve over there. 61 00:07:22,160 --> 00:07:26,720 So this this what is the physical implication of this simple equation is that. 62 00:07:31,720 --> 00:07:38,520 Physics is the same. Here is their. 63 00:07:40,480 --> 00:07:48,280 Now, that's not always the case. If. If that were a clock. 64 00:07:48,820 --> 00:07:56,140 That were a clock. And we let it evolve on the floor. Until until tomorrow. 65 00:07:56,410 --> 00:08:00,310 And then read it well and then moved it up here. 66 00:08:00,880 --> 00:08:08,200 Well, somewhere higher up here. We wouldn't have the same situation as if we let it evolve until tomorrow up there. 67 00:08:08,680 --> 00:08:15,819 Because. Because clocks the gravitational potential down on the floor is lower than it is up there. 68 00:08:15,820 --> 00:08:18,880 So a clock up there will evolve faster than a clock down there. 69 00:08:21,520 --> 00:08:25,610 So it is by no means obvious. 70 00:08:25,960 --> 00:08:32,890 It's not necessarily the case that that it doesn't matter where you conduct your experiments, 71 00:08:32,890 --> 00:08:37,660 that evolving it in one place and then shoving it and then moving it somewhere else 72 00:08:37,660 --> 00:08:41,860 is going to give you the same results as shoving it somewhere else now and then, allowing it to evolve with that other place. 73 00:08:45,860 --> 00:08:52,900 This being the same here and there is is is a statement about the the homogeneity. 74 00:08:52,910 --> 00:08:56,180 So when this is the case, it's a statement about the homogeneity of space. 75 00:08:56,720 --> 00:09:02,600 It's it's a right. And we would say and physicists are of the view that that. 76 00:09:03,860 --> 00:09:07,729 Ultimately physics has to be the same here and there. 77 00:09:07,730 --> 00:09:11,389 And the reason and the reason that the clock evolves on the floor in a different 78 00:09:11,390 --> 00:09:16,730 way from on the table is because not because of any homogeneity of space, 79 00:09:16,730 --> 00:09:20,030 but the fact that is a dirty, great planet here. 80 00:09:20,330 --> 00:09:23,960 We're 8000 miles or whatever it is from the centre of the earth, 81 00:09:24,230 --> 00:09:31,790 and it's the relative movement of the earth and the clock which has changed the circumstances, not the homogeneity of space. 82 00:09:31,800 --> 00:09:39,740 So we're completely wedded to the concept that fundamentally space is the same everywhere, 83 00:09:39,740 --> 00:09:43,100 and therefore, fundamentally, this should be the case should be the case. 84 00:09:43,940 --> 00:09:47,210 If, if, if if your system is isolated. 85 00:09:50,710 --> 00:09:57,850 We say that. In other words, we say that when this principle is not observed, it's the reason it's not observed is your system. 86 00:09:57,850 --> 00:09:59,020 Johnny isn't isolated. 87 00:10:00,530 --> 00:10:06,800 In the case of the of the clock on the floor there, it's obvious what the court what they're not isolated in this is it's the dirty group planet. 88 00:10:07,310 --> 00:10:09,560 But in other circumstances it might be more subtle. 89 00:10:11,210 --> 00:10:19,010 But we would we conjecture that you will be able to find something which is violating the isolate, you know, which is which is affecting it. 90 00:10:19,010 --> 00:10:23,300 Which is which is violating its isolation. 91 00:10:24,770 --> 00:10:34,940 Okay. So where all this commuting of operators is associated with something being conserved, that something is momentum. 92 00:10:36,480 --> 00:10:39,930 It's also associated with a statement about. 93 00:10:41,640 --> 00:10:51,870 Invariance of physics on translations. So so we have a sort of set of ideas like this commuting. 94 00:10:54,110 --> 00:11:04,800 Well. P with h well, so p comber h is connected to conserved. 95 00:11:06,480 --> 00:11:14,500 Momentum. Which is itself connected to uniformity. 96 00:11:18,610 --> 00:11:23,200 Of space. Which is the same thing as symmetry under translation. 97 00:11:31,800 --> 00:11:43,650 And this is a set of three sort of separate things which are tightly connected by mathematics and basic principles of physics. 98 00:11:49,910 --> 00:11:57,230 We similarly if we if it's the case that say Jay Z comma H. 99 00:11:57,920 --> 00:12:02,900 So this is the generator of rotations around the Z axis, if that's equal to nought. 100 00:12:03,380 --> 00:12:11,090 So I need to have a nought equals here then that is associated with conservation in classical physics, 101 00:12:11,090 --> 00:12:14,780 that's associated with the conservation of angular momentum. 102 00:12:21,730 --> 00:12:31,900 Which is why we want to call this the angular momentum operator, which is associated with the result of space. 103 00:12:37,660 --> 00:12:43,210 So it's clearly the case that. A compass. 104 00:12:43,220 --> 00:12:47,240 A compass behaves differently. 105 00:12:47,270 --> 00:12:50,540 If you oriented east, west or north south. Right. 106 00:12:51,170 --> 00:13:00,210 It's. Of. Because because on the surface of the earth, on account of the Earth's magnetic field, 107 00:13:00,600 --> 00:13:05,640 the physics of space is not isotropic from from the perspective of a compass needle. 108 00:13:06,560 --> 00:13:11,570 And it's associated with. And as a consequence of that it's angular momentum. 109 00:13:11,570 --> 00:13:18,080 Operator will not compute with the Hamiltonian of the compass model and its angular momentum will not be conserved. 110 00:13:18,080 --> 00:13:21,500 That's why it swings to and fro around the North Pole when you let it go. 111 00:13:21,830 --> 00:13:36,809 Magnetic north. And he is on the momentum thing. 112 00:13:36,810 --> 00:13:45,570 Just remember what Newton said about bodies moving in a straight line, etc. He fundamentally said isolated bodies have conserved momentum. 113 00:13:45,570 --> 00:13:52,530 And so there already he was he was in fact, connecting the conservation momentum to the to the eyes of space. 114 00:13:52,530 --> 00:14:10,520 He had that concept of an isolated body. So so in general, we're always interested in finding these operators, 115 00:14:10,610 --> 00:14:14,810 these observables which commute with the Hamiltonian and in general it's hard to find. 116 00:14:15,650 --> 00:14:22,530 So in general, it's hard to find. The operators that we don't have a system. 117 00:14:22,530 --> 00:14:26,009 Unfortunately, for finding operators that can meet with the Hamiltonian, 118 00:14:26,010 --> 00:14:31,530 the best system we've in fact got is to look at the at the uniformity of the physics, 119 00:14:31,530 --> 00:14:36,030 to say to ourselves, can I see any reason why the system should be different? 120 00:14:36,330 --> 00:14:42,270 The behaviour of systems should be different. If I rotated where if I translate it or do some other thing to, to it. 121 00:14:47,170 --> 00:14:54,840 So observables. Commuting with age. 122 00:15:00,780 --> 00:15:09,540 But here's an example. When you when you can spot one, if you have any particles that interact with each other, nothing else. 123 00:15:14,300 --> 00:15:25,670 Oops into egg. Then you have the Hamiltonian of this system. 124 00:15:26,030 --> 00:15:30,500 Is the sum API squared over to him. 125 00:15:30,860 --> 00:15:36,440 I summed over particles. Hi. 126 00:15:36,530 --> 00:15:40,250 So this index here enumerates the particles plus. 127 00:15:40,490 --> 00:15:44,720 So that's the kinetic energy of each particle. Some of the particles makes the Hamiltonian to the whole system. 128 00:15:45,050 --> 00:15:48,200 And then that's time. That's, that's going to that. 129 00:15:48,200 --> 00:15:51,650 We have to add the potential energy of interaction between the particles, 130 00:15:52,580 --> 00:15:59,060 which will be the sum of a pairs of particles which we can get by saying that J is less than I. 131 00:16:00,020 --> 00:16:05,419 These are the vector positions of the particles. So there's some, there's some interaction potential between these particles. 132 00:16:05,420 --> 00:16:08,570 They interact in pairs and this, in this, in this, in this picture. 133 00:16:10,550 --> 00:16:16,760 So this would be the Hamiltonian of these particles which are interacting in some arbitrary way with each other, flows that interact in pairs. 134 00:16:17,840 --> 00:16:24,950 What we can say is that is that h is its invariant. 135 00:16:24,950 --> 00:16:37,279 This expression is manifestly the same. If x I goes to x, i plus a, if you simply add a vector A to all the locations of the particles, 136 00:16:37,280 --> 00:16:42,439 long as you shove the whole system along by a vector a then the arguments of 137 00:16:42,440 --> 00:16:47,030 all of these interactions stay the same and you don't affect the momentum. 138 00:16:47,210 --> 00:16:50,690 So H is invariant. And what does that tell you? 139 00:16:50,990 --> 00:16:54,559 That tells you that the generator of this. 140 00:16:54,560 --> 00:17:02,460 Of this. Of this transformation is going to be a conserve quantity. 141 00:17:02,940 --> 00:17:08,590 So this so this transformation. Well, it implies. 142 00:17:10,340 --> 00:17:13,970 Conservation. Of the generator. 143 00:17:16,680 --> 00:17:24,900 Which is going to be the the total momentum being the sum of the momenta of the individual particles. 144 00:17:26,590 --> 00:17:31,419 Which of course we recognise as is the total momentum of this system is going to be 145 00:17:31,420 --> 00:17:35,170 conserved because action and reaction or equal and opposite back to back to what? 146 00:17:35,170 --> 00:17:44,770 Isaac Newton. These points you haven't seen probably made in this way before. 147 00:17:45,970 --> 00:17:53,800 But it is. I would like to make the point that. They are actually very fundamental points of physics. 148 00:17:53,950 --> 00:17:57,770 They are not peculiar. They're not special to quantum mechanics in classical physics. 149 00:17:57,790 --> 00:17:59,740 All of these statements remain true. 150 00:18:00,010 --> 00:18:07,090 It's just that when you do elementary mechanics, you don't have the machinery at hand to see the connection between symmetry and conserved quantities. 151 00:18:08,560 --> 00:18:13,960 These are really very basic points which are true in quantum mechanics, but they're also true in classical physics. 152 00:18:14,200 --> 00:18:23,200 But we have now the apparatus, so we can see these things rather more clearly than we can in classical physics. 153 00:18:23,230 --> 00:18:27,730 So we now have time to cycle back to something to what I skipped, which was. 154 00:18:31,540 --> 00:18:49,590 Which is motion in a magnetic field. This is a particularly important topic because an awful lot of quantum mechanics was developed. 155 00:18:51,000 --> 00:18:56,010 Historically, it was developed by sticking atoms into magnetic fields. 156 00:18:56,340 --> 00:19:00,510 It's obviously also an important topic in the sense that. 157 00:19:03,800 --> 00:19:08,210 We use magnetic fields in an awful lot of in an awful lot of devices. 158 00:19:08,240 --> 00:19:13,830 And people also now stick their crystals in magnetic fields to see what happens. 159 00:19:13,840 --> 00:19:18,530 So it's still a it's still an important way of probing systems when you're trying 160 00:19:18,530 --> 00:19:24,169 to understand systems which whose physics is is based on quantum mechanics. 161 00:19:24,170 --> 00:19:26,150 And it's very important to understand how this happens. 162 00:19:26,540 --> 00:19:36,050 And there's a fundamental difficulty we have to address up front, which is what we need to know is how to modify the Hamiltonian. 163 00:19:38,990 --> 00:19:42,950 Right. Because in quantum mechanics you put the physics into the Hamiltonian. 164 00:19:42,950 --> 00:19:47,900 The Hamiltonian tells you what forces are acting, what the system consists of. 165 00:19:48,900 --> 00:19:53,340 It encodes what the physical laws are. 166 00:19:55,390 --> 00:20:01,210 For your system. So if you switch on a magnetic field, it must be that it's changing the Hamiltonian somehow. 167 00:20:01,900 --> 00:20:04,720 So the question is, so how is it changing the Hamiltonian? 168 00:20:06,070 --> 00:20:15,910 And if you take the view that H is equal to P squared over two M plus V because you've got some particle, 169 00:20:15,910 --> 00:20:22,360 then you're in trouble because there's no magnetic contribution in the potential energy. 170 00:20:28,570 --> 00:20:30,760 Because the Lorentz force never does any work. 171 00:20:31,060 --> 00:20:39,700 The Lorenz force, the cross b is perpendicular to v so v dot v cross be identically vanishes, and the Lorenz force never does any work. 172 00:20:40,000 --> 00:20:46,930 So it can never contribute to the potential energy of your system. And therefore you can't look for you can't look for magnetic contributions in here. 173 00:20:49,180 --> 00:20:57,450 So it turns out that. And you need to do it because magnetism is a relativistic correction to electric statics, right? 174 00:20:58,170 --> 00:21:00,120 Fundamentally, that's what it is and I think it's one of them. 175 00:21:00,510 --> 00:21:08,129 I'm always amazed and I don't I don't think I really understand why it is that our electoral devices overwhelmingly use this, 176 00:21:08,130 --> 00:21:11,250 you know, your vacuum cleaners, your disk drive, your. 177 00:21:12,180 --> 00:21:16,460 I mean, we make the electricity, in fact, using a relativistic correction to electrostatic. 178 00:21:16,950 --> 00:21:25,339 We do almost nothing with electrostatic. There are a few electric a few scientific instruments use like electrostatic drives but 179 00:21:25,340 --> 00:21:30,739 it's it's it's almost an unused you know Coulomb so is almost unused except to get 180 00:21:30,740 --> 00:21:34,250 the electrons to go down the wires in order to generate this relativistic correction 181 00:21:34,250 --> 00:21:38,600 because they're moving at a slightly different speed from the ions in the wires anyway. 182 00:21:38,600 --> 00:21:43,250 So, so but it is a relativistic correction to electric statics. 183 00:21:44,090 --> 00:21:49,639 And so in order to, to find out how to change your Hamiltonian, you really need to do relativity. 184 00:21:49,640 --> 00:21:52,790 That's the proper place to look. And I'm not going to be able to derive this for you. 185 00:21:53,090 --> 00:22:00,710 I'm going to be able to tell you what it is, which is what we need to do is replace that P by P minus the charge on the particle. 186 00:22:08,450 --> 00:22:14,930 So when we have a magnetic field, we put it in by replacing P in our original Hamiltonian by P minus Q. 187 00:22:15,440 --> 00:22:19,430 What is the charge on your particle? 188 00:22:20,900 --> 00:22:29,720 And of course, B is the curl of A, so a is the magnetic back to potential that generates the magnetic field. 189 00:22:30,260 --> 00:22:37,190 So I'm not really able to justify this because to, to, to explain why this should be so we need to do some relativity, 190 00:22:37,190 --> 00:22:41,720 which is way out of scope for, for the quantum mechanics. 191 00:22:41,840 --> 00:22:45,469 But what we what I should do with this is use Ehrenfest theorem to convince you. 192 00:22:45,470 --> 00:22:54,140 This gives you that this gives us the classical equations of motion in the magnetic field and ultimately. 193 00:22:55,600 --> 00:23:00,070 You know, only experiment can tell you whether this is right or wrong. So let's let's let's use Aaron first. 194 00:23:04,010 --> 00:23:14,180 To recover classical physics out of this. So what we have is i h bar dvd t oops dvd t of the expectation value of x i. 195 00:23:16,290 --> 00:23:22,410 What's that? That's equal to the expectation value of x, comma h. 196 00:23:27,000 --> 00:23:31,240 We're going to will we'll drop this because we're not really interested for the moment. 197 00:23:31,260 --> 00:23:34,649 We're not interested in in V, which would contain, for example, 198 00:23:34,650 --> 00:23:38,100 the electrostatic interactions, the interactions with the electric field, if there were any. 199 00:23:38,100 --> 00:23:43,530 Let's just let's not worry about it. Let's just take it that what we have is a particle moving in a magnetic field. 200 00:23:43,860 --> 00:23:47,490 So I want to take this to be the Hamiltonian, to keep life simple. 201 00:23:47,760 --> 00:24:02,160 So what is this? This is one over two m expectation value of x i comma p minus q a squared comitato. 202 00:24:03,770 --> 00:24:08,210 ABC. Now we know how to take combat cases. 203 00:24:08,810 --> 00:24:11,200 Why does x i not commute with this? 204 00:24:11,210 --> 00:24:17,360 It doesn't compute with this because it contains the momentum operators while in particular it contains the ith momentum operator. 205 00:24:19,730 --> 00:24:27,200 And this is going to be one over two m if we're pedantic, we could do it more quickly than this. 206 00:24:29,870 --> 00:24:34,580 This will commute. This is there are two of these couple together. It'll commute with the first one. 207 00:24:35,630 --> 00:24:39,530 We should do the commentator with the first one. Now X is going to commute with a. 208 00:24:39,950 --> 00:24:52,729 We're going to have that x comma a equals nought because the this vector potential is a function of x write it to the vector potential depends on x, 209 00:24:52,730 --> 00:24:55,820 it varies with x. Therefore it is a function of the operator x. 210 00:24:56,570 --> 00:25:02,750 So X is going to commute with it. So the reason it's going to hit with this bracket is because it contains p. 211 00:25:03,440 --> 00:25:13,790 So we're going to have x x i comma p, the vector p dotted in to p minus q a. 212 00:25:15,560 --> 00:25:18,590 Close brackets. That's one of the two terms. 213 00:25:18,590 --> 00:25:23,030 And then, unfortunately, there's there's another term which will in fact be identical. 214 00:25:23,120 --> 00:25:28,100 But just to be pedantic, let's get it. Let's keep it right. There's going to be P minus Q A. 215 00:25:30,820 --> 00:25:34,430 Dot x i. Com up. 216 00:25:36,770 --> 00:25:42,050 All right. So what we've done is regarded this as P minus times P dotted into P minus Q A, 217 00:25:42,500 --> 00:25:47,420 which is a product we've used the rule for doing the commentator on a product to the commentator on the first term, 218 00:25:47,420 --> 00:25:51,379 leave the second alone, that's that. Then leave the first time alone and do this. 219 00:25:51,380 --> 00:25:57,710 Commentator On the second one and the commentators on these brackets reduced media p because 220 00:25:58,250 --> 00:26:10,010 of that this so this product could be written as a sum over K of PK dot PK minus Q K Right. 221 00:26:10,520 --> 00:26:19,970 And this commentator is going to be nothing except when K equals I when this will be an h bar 222 00:26:20,090 --> 00:26:29,960 which will cancel that h bar and we'll discover that dvt t of x ii is equal to this h bar. 223 00:26:30,170 --> 00:26:36,049 Is is is a mere number. It'll commute with this. So we don't need to worry this this term is going to generate the same as that. 224 00:26:36,050 --> 00:26:45,140 So this gives me a one over M of P minus P-I minus q i. 225 00:26:49,980 --> 00:26:53,969 So this what this is telling us is that the classical velocity, 226 00:26:53,970 --> 00:26:59,879 because the rate of change of the expectation value, the position is what we would call the classical velocity. 227 00:26:59,880 --> 00:27:07,680 The expectation by the velocity, if you like, is not equal to the momentum over M It's equal to the momentum minus Q a over m. 228 00:27:13,880 --> 00:27:19,330 Or alternatively, it's telling you that pie is equal to m v. 229 00:27:19,330 --> 00:27:24,319 I always write these what their expectation values here this is. 230 00:27:24,320 --> 00:27:28,670 This is their expectation values here, right? This was always expectation value. 231 00:27:29,210 --> 00:27:36,890 So what we're discovering is that the expectation value of the momentum is equal to mass times, 232 00:27:36,890 --> 00:27:46,430 expectation of velocity plus Q Times expectation value of the magnetic vector potential at the location of the particle. 233 00:27:46,850 --> 00:27:53,060 And there's a problem on the problem sets that tries to convince you, this is all this is the momentum. 234 00:27:57,960 --> 00:28:04,130 Of the IMAG field. Point is that if you move a charge particle. 235 00:28:05,490 --> 00:28:09,030 You are moving. It's electromagnetic, you're moving. 236 00:28:09,030 --> 00:28:16,620 It's electrostatic field. The electrostatic field causes the magnetic. 237 00:28:16,890 --> 00:28:27,360 The combination of an electric field and a magnetic field endows the makes for a momentum flux in the now electro magnetic field. 238 00:28:27,690 --> 00:28:35,490 And there's a calculation which makes it look as if I think it probably is broadly true that that that. 239 00:28:37,950 --> 00:28:47,229 Yep. The removing charge to get a charge moving, you not only have to give it momentum, but you have to give the field some momentum. 240 00:28:47,230 --> 00:28:51,250 So this really is the total momentum. But the thing is, it's not the field. 241 00:28:51,550 --> 00:28:55,000 The particle is not on its own. It's not the only repository of momentum. 242 00:28:55,180 --> 00:28:59,799 The electromagnetic field is also a repository of momentum anyway. 243 00:28:59,800 --> 00:29:05,110 So so we have this non-trivial relationship now between momentum and velocity. 244 00:29:05,440 --> 00:29:08,709 And again, this is not something special to quantum mechanics. 245 00:29:08,710 --> 00:29:12,610 We've derived this in quantum mechanics, but it's a known result in Hamiltonian mechanics. 246 00:29:12,610 --> 00:29:17,139 Those people who've done A7 may have encountered this formula. 247 00:29:17,140 --> 00:29:24,070 I'm not sure whether it goes quite that far. Let's have a look at the other of the other equation of motion. 248 00:29:24,070 --> 00:29:29,800 We should have a look at which is harder duty of the expectation value of pi. 249 00:29:31,360 --> 00:29:36,910 So. Is going to be a sigh. 250 00:29:37,930 --> 00:29:42,710 P comma h but what's H its peak? 251 00:29:43,330 --> 00:29:54,910 I'm going to write it out now. P.K. minus Q. A K squared some over k commentator sticking another upside. 252 00:29:58,410 --> 00:30:05,820 So this is the commentator of the momentum with the Hamiltonian, where I've now written out the Hamiltonian in Gorey in reasonably gory detail. 253 00:30:09,150 --> 00:30:12,540 Over to him. Over to him. I'm missing a lot of it to him. I not one of it to him. 254 00:30:14,200 --> 00:30:17,290 In all that. That's one over two more times. This is the Hamiltonian. 255 00:30:19,150 --> 00:30:24,160 Why does PI not give you this? Well, obviously, P.E.I. views with Peak, that's a problem. 256 00:30:24,460 --> 00:30:28,360 P.E.I. doesn't commute with this because sitting inside, because this is a function of X. 257 00:30:29,440 --> 00:30:36,520 So when we work this out, we get a one over two M CI big bracket. 258 00:30:37,210 --> 00:30:41,340 We're going to have this thing commuting with that. 259 00:30:41,350 --> 00:30:48,190 So we'll have a minus q p P.E.I. comma a k. 260 00:30:49,390 --> 00:30:57,460 This is going to be some do over K of maybe it'll be better if we put a some over K here. 261 00:30:57,790 --> 00:31:06,790 Got to have one somewhere. Times peak minus Q a k. 262 00:31:07,730 --> 00:31:15,530 So that's that's p commuting with the first of these two of these two brackets and then we will have. 263 00:31:17,550 --> 00:31:27,540 We will have P.K. minus q ak of pi ak. 264 00:31:27,750 --> 00:31:34,950 Commentator And the factor of minus Q from here, close big brackets sticking out. 265 00:31:34,950 --> 00:31:39,150 Another sign. So this is a disgusting mess that we have. 266 00:31:40,580 --> 00:31:44,159 And now we have to address the question of, so what is this comitato? 267 00:31:44,160 --> 00:31:47,250 What is pi, comma, ak? 268 00:31:47,270 --> 00:31:50,760 We need it. We need it in two slots. We need it here and we need it here. 269 00:31:53,150 --> 00:31:59,540 Well, this is we now use our rule for doing the commentator of a function of X. 270 00:31:59,690 --> 00:32:02,840 We use previously almost the rules for a function of P. 271 00:32:04,280 --> 00:32:10,640 The rule was that this is equal to the a k by the x. 272 00:32:12,330 --> 00:32:16,520 High Times. The Communist commentator p comma exi. 273 00:32:20,450 --> 00:32:25,340 Right. The reason this isn't. This is a function of exi. That's why this computer fails to vanish. 274 00:32:26,270 --> 00:32:34,999 And we derived this rule quite early on that you can you can buy Taylor series expanding your function. 275 00:32:35,000 --> 00:32:38,690 You can convince yourself that this is true, that we just have a derivative times. 276 00:32:38,690 --> 00:32:45,200 The commentator with respect to whatever it is we taking the derivative with respect to this is minus h bar. 277 00:32:47,210 --> 00:32:51,820 So. By the I. 278 00:32:54,960 --> 00:32:59,190 So we're going to get some ice balls, which we can cancel over there. 279 00:32:59,190 --> 00:33:07,530 So we're going to have the DVD t of PI, the rate of change of momentum, which should be equal to false all being. 280 00:33:07,530 --> 00:33:11,280 Well, this is turning out to be. 281 00:33:11,670 --> 00:33:19,440 Oh, yeah, sorry. Yeah. So we're going to have a one over two now we can take out a factor of Q of A to M This minus sorry 282 00:33:19,440 --> 00:33:27,089 is going to cancel that minus sign that Q I've taken outside the sum over K has not collapsed. 283 00:33:27,090 --> 00:33:30,090 No, it's the left. Yep. 284 00:33:31,740 --> 00:33:44,970 So we're going to have a summer of okay, what of we're going to have a K by TXI for this one here. 285 00:33:45,300 --> 00:33:54,810 We've got all the factors, peak minus Q arc and we're going to have essentially the same thing. 286 00:33:54,810 --> 00:34:03,299 But in the reverse order, peak minus q a K of the K by the x, 287 00:34:03,300 --> 00:34:09,930 i close the brick bracket and stick a matching cat upside on the outside to take the expectation value. 288 00:34:11,280 --> 00:34:20,070 So unfortunately, I cannot combine these two terms as they stand into one term because this is a function of x which refuses to compute with that p. 289 00:34:21,120 --> 00:34:28,200 Similarly this one. So so this thing is trapped on the left side of P and that one trapped on the right side of P and I can't combine them. 290 00:34:29,340 --> 00:34:33,120 And then in quantum mechanics, this is as far as I can as I can go. 291 00:34:33,480 --> 00:34:40,670 I now have to. So this is a this is a respectable, totally aboveboard quantum mechanical calculation to go further, 292 00:34:40,690 --> 00:34:44,459 I, I have to say, well, look, what am I trying to do? 293 00:34:44,460 --> 00:34:47,550 I'm trying to recover the Lorentz force for you. 294 00:34:47,550 --> 00:34:52,980 I'm trying to show that the classical in this is predicting the correct classical physics. 295 00:34:53,970 --> 00:34:57,780 If I'm predicting the correct classical physics, I can. 296 00:35:00,310 --> 00:35:06,070 If I talk about the classical physics, each of these operators can get replaced by its own expectation value. 297 00:35:06,080 --> 00:35:13,150 So the issue here is that here I have to take the expectation value of a product of one operator on another operator, 298 00:35:14,500 --> 00:35:20,829 and such an expectation value is not automatically the same as the product of the expectation value of this. 299 00:35:20,830 --> 00:35:22,570 On the expectation value of that, 300 00:35:23,110 --> 00:35:30,100 because fluctuations in this operator may be correlated with fluctuations in that in that sort of quantum fluctuations. 301 00:35:31,030 --> 00:35:34,989 But if we're in the classical limit, we we don't worry about these fluctuations. 302 00:35:34,990 --> 00:35:40,330 We assume that they all they all average wage zero like the interference pattern associated with the bullets. 303 00:35:40,330 --> 00:35:44,710 I mean, the fluctuations average away. We're just left with the mean value of the mean. 304 00:35:45,190 --> 00:35:52,540 So we now replace this product with a product of the expectation of the product, with a product of the expectation values. 305 00:35:52,780 --> 00:35:59,680 And then these become in numbers. So this becomes an expectation value of this operator, the expectation of the value of this number. 306 00:35:59,980 --> 00:36:03,940 And then of course, the numbers can be arranged in either order and I can stop fussing. 307 00:36:05,630 --> 00:36:13,160 I can stop fussing about about this so we can we now say in the classical limit. 308 00:36:14,470 --> 00:36:24,100 We've specialising now to the classic limit when we can neglect fluctuations, we can write this is Q over. 309 00:36:24,100 --> 00:36:27,100 M Because I'm going to combine these two terms, 310 00:36:27,550 --> 00:36:39,280 the sum over K of the expectation value of decay k by the Z times the expectation value of peak minus q a k. 311 00:36:42,200 --> 00:36:48,170 Now we can simplify again because this expectation value p, k minus Q. 312 00:36:49,610 --> 00:36:56,299 Remember we showed above. We honestly showed above without any fudging was equal to the mass times. 313 00:36:56,300 --> 00:37:00,290 The expectation of value of the velocity. Well. Well, that's. That's unjust. 314 00:37:00,410 --> 00:37:06,380 Yeah, right. So this thing here can be replaced by M the K. 315 00:37:08,600 --> 00:37:13,540 And the EMS cancel while we're about it. 316 00:37:13,550 --> 00:37:18,600 Why don't we replace this p I with M? 317 00:37:19,200 --> 00:37:24,530 Well, with what we get from up there, I've lost it. Here we go. It's in the VII minus. 318 00:37:24,770 --> 00:37:41,120 Sorry. Plus Kua. So this now comes down to DVD T of M VII plus q expectation of a I that's using that 319 00:37:41,240 --> 00:37:46,160 respectable formula up there for the relationship between velocity and momentum. 320 00:37:47,030 --> 00:37:50,390 Yes, that's correct. And that is going to be. 321 00:37:50,630 --> 00:38:02,270 Q Because the M's are going to cancel the sum over K of D a K by the X II times. 322 00:38:02,870 --> 00:38:13,309 What did we say was weak? And we ought to put an expectation value on around everything because we are dealing now with expectation values. 323 00:38:13,310 --> 00:38:16,310 We've explicitly gone to the classical regime. 324 00:38:21,600 --> 00:38:25,430 Okay. So we're nearly there. It doesn't probably look as if. What are we trying to get? 325 00:38:25,440 --> 00:38:28,920 I'm trying to get that mass times acceleration is equal to V. 326 00:38:30,040 --> 00:38:35,510 Crosby. And it may look as if I'm still some way from that, but it's not so bad, actually. 327 00:38:37,520 --> 00:38:42,650 Why? So what? On the left, what we have on the left here is the rate of change, 328 00:38:43,040 --> 00:38:52,160 of obviously the velocity and the and the vector potential evaluate is at the location of the particle, 329 00:38:52,400 --> 00:38:57,140 not just anywhere else, but at the location of the particle. So suppose we have a static field. 330 00:38:57,890 --> 00:39:09,310 Static B field. So that means that the partial derivative of a with respect to time can be taken to vanish. 331 00:39:10,630 --> 00:39:16,470 If the if this thing were nonzero, it would generate an electric field that would be quick. 332 00:39:17,020 --> 00:39:21,850 And then you know right of time varying magnetic field creates by Faraday's law 333 00:39:21,940 --> 00:39:27,339 creates a curly field and we that that leads to more complicated equation of motion. 334 00:39:27,340 --> 00:39:35,050 So we got we're just in static B fields so that the rate of change of the magnetic vector potential at any given point is zero. 335 00:39:35,230 --> 00:39:43,810 But this time derivative is not zero because the particle is moving and, and sensing the impact the, the vector potential at different locations. 336 00:39:44,560 --> 00:39:52,810 So what we have is that d by d t of a i is equal to what is it equal to? 337 00:39:52,810 --> 00:39:55,870 It's equal to the by the chain rule. 338 00:39:56,050 --> 00:40:01,330 It's equal to the x k by d t sorry. 339 00:40:01,330 --> 00:40:08,410 That should be a total total derivative d by t times d i by the x k. 340 00:40:09,420 --> 00:40:16,260 So the reason that this quantity is changing is because the place where we're making the measurements is changing at this rate, 341 00:40:16,260 --> 00:40:19,020 and this is the rate at which a change is with location. 342 00:40:22,130 --> 00:40:35,300 So what we now have is the m d vii by e t e mass times acceleration is equal to Q Q is going to be a factor Q on the right. 343 00:40:35,660 --> 00:40:43,010 I write down the terms. I've already got some of a k k by the x i. 344 00:40:45,360 --> 00:40:50,300 VK and then I'm transferring from the left side. 345 00:40:51,470 --> 00:41:04,850 This time's Q Right. So I have and it's going to come minus this is v k and this is the I by the x k. 346 00:41:08,860 --> 00:41:12,300 Street speaking. This bracket should be here because that summation sign is over. 347 00:41:12,690 --> 00:41:20,019 Is over. Both these both these signings have. Now this is actually equal to. 348 00:41:20,020 --> 00:41:26,770 Q The cross B ice component. 349 00:41:27,280 --> 00:41:38,350 Uh, well, because it's V cross. Ask yourself what what this would. 350 00:41:38,830 --> 00:41:47,350 I mean, just I claim that this is true. Let us see whether it is true, what we in order to expand this vector triple product, 351 00:41:47,350 --> 00:41:51,640 we would say it was this thing does it with this thing in the direction of that thing. 352 00:41:52,330 --> 00:42:11,150 So if I expand this, I get Q. This thing dotted with this thing that means a sum over k a VK VK K direction of this thing gives me a nebula. 353 00:42:11,320 --> 00:42:20,799 I because I'm trying to calculate the ice component and then minus this thing dotted with this thing, direction of that thing. 354 00:42:20,800 --> 00:42:23,800 So that's a VK Nebula K. 355 00:42:25,670 --> 00:42:38,980 A I. It's a little bit of a complicated vector triple product because this is a differential operator and it is operating only on this, never on this. 356 00:42:39,000 --> 00:42:43,860 So that's why I've written them in that form. It's this thing does it, this thing, direction of that thing. 357 00:42:44,100 --> 00:42:50,880 But this is only working on that. And then it's this thing dotted with this thing, direction of that thing that's nice and easy. 358 00:42:51,720 --> 00:42:57,450 And I think you can see that this term. Is this term and this term? 359 00:42:57,990 --> 00:43:01,230 Is this term with. If you move that around in back. Right. 360 00:43:01,950 --> 00:43:07,229 These these two terms are the same. So we have indeed recovered mass times. 361 00:43:07,230 --> 00:43:12,020 Acceleration is equal to Lorentz force. In the classical limit. 362 00:43:14,580 --> 00:43:20,050 Well, I think that's really all that I want to do. Yeah, that's all I want to do. 363 00:43:20,670 --> 00:43:25,260 That justifies provisionally the use of. 364 00:43:25,450 --> 00:43:29,120 So this Hamiltonian. Where was it? P minus. 365 00:43:33,370 --> 00:43:36,820 P minus A all squared over to him being the Hamill. 366 00:43:37,030 --> 00:43:47,500 That change in the Hamiltonian introduces a magnetic field into the physics, and we will use that when discussing atoms. 367 00:43:47,890 --> 00:43:51,219 Down, down the track. And if you look at the back end of chapter three, 368 00:43:51,220 --> 00:43:58,090 you can see there are some quite entertaining things you can do with the with the motion of a particle in a uniform magnetic field. 369 00:43:59,230 --> 00:44:05,740 When it turns out that you can recycle, you can recycle the physics well, 370 00:44:06,250 --> 00:44:11,230 you can recycle the formalism in the mathematics that we did for the harmonic harmonic oscillator. 371 00:44:11,530 --> 00:44:14,830 You can recycle it for this uniform magnetic field case. 372 00:44:15,070 --> 00:44:20,800 The basic principle is that if you if you have a uniform B field. 373 00:44:27,320 --> 00:44:31,820 And a non relativistic particle moving in a uniform charged particle moving in a uniform B field. 374 00:44:33,170 --> 00:44:44,270 You can have the orbits of circles, the particle circles around in this uniform B field with some radius that depends on its speed. 375 00:44:44,900 --> 00:44:48,620 If you have a fast particle, it goes round. It goes round. 376 00:44:49,040 --> 00:44:52,170 You know, we have we have empty square of all. 377 00:44:56,190 --> 00:45:01,200 Is equal to Q the b b. 378 00:45:03,780 --> 00:45:07,050 So we have that that v. 379 00:45:09,090 --> 00:45:15,629 Over R is equal to cube of m is equal to than the more frequency. 380 00:45:15,630 --> 00:45:22,470 So the the the the the angular frequency of which the particle goes on its orbit 381 00:45:22,890 --> 00:45:26,340 is depends on the strength of the magnetic field and the charge in the mass, 382 00:45:26,340 --> 00:45:29,370 but not on the energy. It doesn't depend on how fast you're going. 383 00:45:29,670 --> 00:45:33,990 So fast particles go in big circles and take the same time to go around to slow particles. 384 00:45:34,560 --> 00:45:35,760 So you have a characteristic. 385 00:45:35,880 --> 00:45:42,920 All the motion is at some characteristic frequency and that is reminiscent of a harmonic oscillator or it allows allows us to reset that. 386 00:45:42,930 --> 00:45:47,610 The fundamental underlying physical reason why we can solve the problem of motion, 387 00:45:47,610 --> 00:45:53,010 the quantum mechanical problem of motion in a uniform magnetic field using the apparatus of the harmonic oscillator. 388 00:45:54,310 --> 00:45:59,469 So I think you should have I mean, I hope some people will have some fun looking at that in the vacation. 389 00:45:59,470 --> 00:46:02,800 It is very good quantum mechanics. It's it's very important physics. 390 00:46:03,040 --> 00:46:07,959 But unfortunately, we are not going to have time to cover it in the in the lectures. 391 00:46:07,960 --> 00:46:12,970 But magnetic field will be important in in the context of atomic physics. 392 00:46:13,840 --> 00:46:15,160 Okay, so that's it until next time.